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IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE)

[Bis(trifluoroacetoxy)iodo]benzene

CAS: 2712-78-9

Molecular Formula: C10H5F6IO4

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IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE) - Names and Identifiers

Name [Bis(trifluoroacetoxy)iodo]benzene
Synonyms BTI
PIFA
Bis(Trifluoracetoxy)-Iodobenzene
IODOBENZENE BIS(TRIFLUOROACETATE)
Bis(Trifluoroacetoxy) Iodobenzene
BIS(TRIFLUORACETOXY)- IODOBENZENE
[Bis(trifluoroacetoxy)iodo]benzene
[BIS(TRIFLUOROACETOXY)IODO]BENZENE
Iodosobenzene bis(trifluoroacetate)
IODINE, PHENYLBIS(TRIFLUOROACETATO)-
[Bis(trifluoroacetoxy)](phenyl)iodane
IODOBENZENE I,I-BIS(TRIFLUOROACETATE)
IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE)
Phenyliodine(III) bis(trifluoroacetate)
3-iodobenzene-1,2-diyl bis(trifluoroacetate)
CAS 2712-78-9
EINECS 220-308-0
InChI InChI=1/C10H3F6IO4/c11-9(12,13)7(18)20-5-3-1-2-4(17)6(5)21-8(19)10(14,15)16/h1-3H

IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE) - Physico-chemical Properties

Molecular FormulaC10H5F6IO4
Molar Mass430.04
Density1.95g/cm3
Melting Point121-125°C(lit.)
Boling Point267.573°C at 760 mmHg
Flash Point115.624°C
Water Solubilityinsoluble
Solubility Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly)
Vapor Presure0.008mmHg at 25°C
AppearanceCrystalline powder
ColorWhite to pale yellow
BRN764767
Storage ConditionKeep in dark place,Inert atmosphere,2-8°C
StabilityAir and Moisture Sensitive
SensitiveMoisture & Light Sensitive
Refractive Index1.483
MDLMFCD00009672
UseUsed for α-hydroxylation of ketones under acidic conditions, and also used for fluorination reagents.

IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE) - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk Codes36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
S37/39 - Wear suitable gloves and eye/face protection
WGK Germany3
FLUKA BRAND F CODES4.10-8-9-21
HS Code29036990
Hazard NoteIrritant/Keep Cold
Hazard ClassIRRITANT, KEEP COLD,

IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE) - Introduction

Insoluble in water, soluble in organic solvents.
Last Update：2022-10-16 17:24:10

IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE) - Reference Information

Use Used as a multifunctional oxidant; Under acidic conditions, it is used for the direct α-hydroxylation reaction of ketones; In the presence of HF pyridine, it is used as p-fluorinated reagent for 4-alkylphenol, used to synthesize 4-fluorocyclohexane-2, 5-dienone; used for N-acylhydrazone to produce 1,3, 4-Oxadiazole oxidation reaction reagent; used to promote the cyclization reaction of styrylamine to N-alkyl or N-arylindole; dehydrogenation reaction and oxidation reaction reagent; direct conversion of amide to amines (Hoffman Rearrangement) is a new reagent, a key substance for the ordering of carboxyl-terminal peptides; a reagent for desulfurization and acetalization to carbonyl
production method 1.?1.485 grams (5.41 mmol) of iodobenzene dichloride was added to 2.39 grams (10.8 mmol) of potassium trifluoroacetate in a solution of 17 ml of silver. Filtered, the product obtained by lyophilizing the filtrate contains a trace of silver trifluoroacetate. 2. 2g iodobenzene and 4 ml of resteamed trifluoroacetic acid were heated on a water vapor bath for 45 minutes. Pour into ether (50ml), evaporate part of the ether to precipitate yellow and white crystals, and wash with a small amount of ether to wash off the color. 3.20g of diacetic acid iodobenzene is dissolved in 30 ml of hot trifluoroacetic acid to obtain 15g (53%). Bis (trifluoroacetic acid) iodobenzene is crystallized. The first part is dried in a solid sodium hydroxide dryer, which is pure enough. This compound can be recrystallized from acetone-petroleum ether and then cooled to 0 ℃. Another product can be obtained, but it contains diacetate and is seriously impure. In addition, there is a method for electrophilic substitution of tris (difluoroacetic acid) iodine and benzene
Last Update：2024-04-10 22:29:15
IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE)
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Product Name: [Bis(trifluoroacetoxy)iodo]benzene Request for quotation
CAS: 2712-78-9
Tel: +86 0512-68417696
Email: chenmengqi@highfine.com
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Product Name: [Bis(trifluoroacetoxy)iodo]benzene Visit Supplier Webpage Request for quotation
CAS: 2712-78-9
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Mobile: +86-18621343501
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Hefei TNJ Chemical Industry Co.,Ltd.
Product Name: [Bis(trifluoroacetoxy)iodo]benzene Request for quotation
CAS: 2712-78-9
Tel: 0086-551-65418684
Email: sales@tnjchem.com
　　　　 info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840 Click to send a QQ message
Wechat: 189 4982 3763
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Product Name: [Bis(trifluoroacetoxy)iodo]benzene Visit Supplier Webpage Request for quotation
CAS: 2712-78-9
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
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Shanghai Yuanye Bio-Technology Co., Ltd.
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Product Name: [Bis(trifluoroacetoxy)iodo]benzene Visit Supplier Webpage Request for quotation
CAS: 2712-78-9
Tel: 18301782025
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View History
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